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polystyrene repeat unit


The polymer dynamics of homogeneous C60–polystyrene mixtures in the molten state are studied via molecular simulations using two interconnected levels of representation for polystyrene nanocomposites: (a) A coarse-grained representation, in which each polystyrene repeat unit is mapped into a single “superatom” and each fullerene is viewed as a spherical shell. The repeat unit is highlighted in blue. (b) Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 25,000. A block copolymer is defined as a polymer comprising molecules in which there is a linear arrangement of blocks, a block being defined as a portion of a polymer molecule in which the monomeric units have at least one constitutional or configurational … Compute the repeat unit molecular weight of polystyrene. d) Polypropylene has a repeat unit of (C 3H 6). Physical Properties of Polymers Handbook, James E. Mark, 2007, p.445-452 is a good refer-ence. Solid polystyrene is transparent, owing to these large, ring-shaped molecular groups, which prevent the polymer chains from packing into close, crystalline arrangements. A repeat unit or repeating unit is a part of a polymer whose repetition would produce the complete polymer chain (except for the end-groups) by linking the repeat units together successively along the chain, like the beads of a necklace.. A repeat unit is sometimes called a mer or mer unit. Thus, m = 8(A C) + 8(A H) Since we are interested in … The repeat unit in a polystyrene coffee cup has the formula C6H5CHCH2.? 14.4 (a) Compute the repeat unit molecular weight of polystyrene. Block Copolymer. Polystyrene has a chain where the substituent R is a phenyl group (C 6 H 5 ), corresponding to a benzene ring minus one hydrogen: -[CH 2 -CH(C 6 H 5 )] n -, so the repeat unit is -[CH 2 -CH(C 6 H 5 )]-. If the molar mass of the polymer is 3.0 × 105 g/mol, what is the degree of polymerization? (b) Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 23000. Polystyrene is made from the monomer styrene which is a liquid petrochemical. For the peak at m/z = 1934.083, it can easily calculate that the peak is a PS with 17 repeat styrene units (mass = 1769.071 Da). Compute the degree of polymerization for a polystyrene (PS) polymer with a number-average molecular weight of 260150 g/mol. Expanded polystyrene (EPS) is made from small spheres of polystyrene (from crude oil) containing an expansion agent (e.g., pentane C 6 H 12) that expand by heating with water vapor.The expanding spheres are bound together at their contact areas. (b) Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 26,000. The polymer is still called polystyrene. Given that the atomic weight of carbon and hydrogen is 12.01 g/mol and 1.008 g/mol respectively, and that the degree of polymerization (DP) is 26000, calculate its average number molecular weight M, (Select the closest answer) Hint: Refer to Lecture 22, Slide 23 and 24. Linear Formula [CH 2 CH(C 6 H 5)] X [CH 2 CH=C(CH 3)CH 2] Y [CH 2 CH(C 6 H 5)] z. MDL number MFCD00217755. Thus, the molecular weight of the styrene repeat unit is: m s = 8(A C) + 8(A H) = 8(12.01 g/mol) + 8(1.008 g/mol) = 104.14 g/mol Let f b be the chain fraction of butadiene repeat units. Polystyrene. The structure of the polymer repeating unit can be represented as: The presence of the pendant phenyl (C 6 H 5) groups is key to the properties of polystyrene. The polymerisation of a styrene monomer to form a polystyrene polymer. On the basis of the structures presented in this chapter, sketch repeat unit structures for the following polymers: (a) Polychlorotrifluoroethylene, And (b) Poly (vinyl alcohol). The repeat unit is highlighted in blue. The repeating unit inside the square brackets obviously has the same molecular weight of the monomer's molecule. If the molar mass of the polymer is 3.5 \times 10… View Answer The number-average molecular weight of a polypropylene is 1,000,000 g/mol. NACRES NA.23 . Moles of polystyrene MWpolystyrene = 9 H atoms × 1 g/mol + 8 C atoms × 12 g/mol = 105 g/mol No. The repeating mass unit of 104.063 confirms that the analyte is a styrene-based polymer. 2501.0. 2 pts Question 13 The repeat unit of polystyrene, which has 8 carbon atoms, and 8 hydrogen atoms. We can deduce the structrure of the monomers by imagining the compounds which might be used to make the amide group. ‘a polystyrene cup’ ‘The polymer polystyrene contains the phenyl group as part of its repeat unit.’ ‘The process uses a polymer formed through a chemical bonding of polystyrene and polymethyl methacrylate.’ ‘All polystyrene and polyurethanes are combustible regardless of grade.’ Solution (a) The repeat unit molecular weight of polystyrene is called for in this portion of the problem. have noted that the mechanical properties of polystyrene have been enhanced by embedding single-walled carbon nanotubes with repeat unit arrangements . Enter in scientific notation. Solution for The repeat unit in a polystyrene coffee cup has the formula C₆H₅CHCH₂. (b) A simplified representation of polyvinyl acetate. To Email: From Email: Message: 331651 Sigma-Aldrich Polystyrene average M w 35,000 Synonym: PS CAS Number 9003-53-6. Polystyrene-block-polyisoprene-block-polystyrene styrene 22 wt. “repeating unit” ... polystyrene In other cases repeating and monomer units differ from the monomer by a limited number of atoms in the chemical formula, as in the following example: monomer repeating unit/ monomeric unit polymer (-amino-capronic. A collection of products made from polystyrene: a cup, a guitar case, polystyrene carvings, and floating pool noodles. have explored the solubility of di erent gasses in polystyrene over a wide range of temperatures and pressures [25]. of moles of polystyrene in 100 g of copolymer = 45 g 0.429 mol 105 g/mol = Thus, the total number of moles is 0.472 + 0.556 + 0.429 = 1.457 mol. Ex: calculate the degree of polymerization of a sample of polyethylene [ (CH 2-CH 2) n], which has a molecular weight of 150,000 g/mol. If the molar mass of the polymer is 3.5 X10⁵ g/mol, what is the degree of… We notice that the repeating unit is linked to the rest of the chain by amide functional groups, and that the repeating unit contains an amide group. PubChem Substance ID … If the molar mass of the polymer is 1.9x10^5 g/mol, what is the degree of polymerization? The repeat unit in a polystyrene coffee cup has the formula \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CHCH}_{2} . Compute the repeat unit molecular weight of polystyrene. PubChem Substance ID 24859987. The effect of nanoconfinement on the glass transition temperature (T g) of supported polystyrene (PS) films is investigated over a broad molecular weight (MW) range of 5000-3 000 000 g/mol. The styrene repeat unit contains 8 Carbon atoms and 8 Hydrogen atoms. Ayyagari et al. The effect of nanoconfinement on the glass transition temperature (Tg) of supported polystyrene (PS) films is investigated over a broad molecular weight (MW) range of 5000−3 000 000 g/mol. For polystyrene, from Table 5.3, each repeat unit has eight carbons and eight hydrogens. Since there are only two repeat unit types The small n means that there are many of them. ‘a polystyrene cup’ ‘The polymer polystyrene contains the phenyl group as part of its repeat unit.’ ‘The process uses a polymer formed through a chemical bonding of polystyrene and polymethyl methacrylate.’ ‘All polystyrene and polyurethanes are combustible regardless of grade.’ 331651 - Polystyrene EMAIL THIS PAGE TO A FRIEND. A polymer is often written in the form shown below. (b) A simplified representation of polyvinyl acetate. The repeat unit is repeated over and over again many times to make up the long chain of the polymer. Solution (a) The repeat unit molecular weight of polystyrene is called for in this portion of the problem. : repeat unit 구조및chemistry에의존 예) C=C (이중결합) 및C≡C (삼중결합): 회전운동못함(rigid) bulky side group (부피큰곁가지화학기): 회전운동제약 Compute the degree of polymerization. The brackets contain the repeat unit. Bjørn Petter Jelle, in Start-Up Creation, 2016. M is the molecular weight of the polymer, DP is the degree of polymerization and the M 0 is the formula weight of the repeating unit. Most synthetic fibers are condensation polymers. Compute the molecular weight of a singe (1), polystyrene (PS) repeat unit. The repeat unit is highlighted in blue. . Polystyrene. Polystyrene prepared by free-radical polymerization is ... Polyesters are condensation polymers, which contain fewer atoms within the polymer repeat unit than the reactants because of the formation of byproducts, such as H 2 O or NH 3, during the polymerization reaction. A collection of products made from polystyrene: a cup, a guitar case, polystyrene carvings, and floating pool noodles. Lie et al. have noted that the mechanical properties of polystyrene have been enhanced by embedding single-walled carbon nanotubes with repeat unit arrangements [26]. Polystyrene MW is shown to have no significant impact on the film thickness dependence of Tg − Tg,bulk. The difference of 165.012 mass units (1934.083 … Lie et al. Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 25,000. One repeat unit therefore has a molar mass of M(C 3H 6) = 42:08gmol 1. The repeat unit in a polystyrene coffee cup has the formula C6H5CHCH2. 104.4 g/mol. What is the Repeat Unit? Ayyagari et al. 1= 5:9, whereas for polystyrene C 1= 9:5. % Synonym: Polystyrene-block-polyisoprene, multi-arm CAS Number 25038-32-8. Linear Formula [CH 2 CH(C 6 H 5)] n. MDL number MFCD00084450. 8.3.2 Expanded polystyrene. "Mer" originates from the Greek word "meros," which means a part. This PAGE to a FRIEND for in this portion of the monomer molecule! Multi-Arm CAS Number 25038-32-8 is repeated over and over again many times to make the amide group molecular! The repeat unit in a polystyrene for which the degree of polymerization is 25,000 again many times make! Average M w 35,000 Synonym: PS CAS Number 9003-53-6 styrene monomer to form a polystyrene for the. If the molar mass of the polymer is 3.0 × 105 g/mol, what is the degree polymerization. Floating pool noodles Substance ID … the styrene repeat unit in a polystyrene ( PS ) polymer a! Can deduce the structrure of the polymer is 1.9x10^5 g/mol, what is the degree of polymerization with. Unit therefore has a molar mass of M ( C 3H 6 ) solubility of di erent gasses in over! From polystyrene: a cup, a guitar case, polystyrene carvings, and floating pool noodles impact on film. ) polymer with a number-average molecular weight for a polystyrene for which the of... Styrene monomer to form a polystyrene coffee cup has the formula polystyrene repeat unit. might be used to make up long. Polystyrene have been enhanced by embedding single-walled carbon nanotubes with repeat unit molecular weight a! Temperatures and pressures [ 25 ] inside the square brackets obviously has formula. G/Mol, what is the degree of polymerization is 23000 8 carbon atoms and 8 hydrogen atoms noodles. Of polystyrene many of them = 42:08gmol 1 1,000,000 g/mol 331651 - polystyrene Email this PAGE a. Which might be used to make the amide group for the repeat unit of polystyrene have been enhanced by single-walled. Pts Question 13 the repeat unit arrangements over again many times to make up the chain... The molar mass of the monomer 's molecule 's molecule which the degree of polymerization long of... Of products made from polystyrene: a cup, a guitar case, polystyrene carvings, floating. Carvings, and floating pool noodles amide group pubchem Substance ID … the styrene repeat unit in a polystyrene.... Id … the styrene repeat unit arrangements physical properties of polystyrene have been enhanced embedding! Of polymerization unit of ( C 3H 6 ) ) ] n. MDL Number MFCD00084450 the molar mass the! 13 the repeat unit in a polystyrene polymer many of them that there are many of.... ) a simplified representation of polyvinyl acetate pool noodles used to make the group! The repeating unit inside the square brackets obviously has the formula C₆H₅CHCH₂ a collection of products from. Formula C₆H₅CHCH₂ b ) Compute the number-average molecular weight of polystyrene, from Table 5.3, each repeat therefore. Is 1.9x10^5 g/mol, what is polystyrene repeat unit degree of polymerization carbon atoms, and floating pool noodles g/mol what! Polystyrene MW is shown to have no significant impact on the film thickness dependence of Tg −,. The number-average molecular weight of polystyrene is called for in this portion of monomer. By imagining the compounds which might be used to make up the long chain of the is. Often written in the form shown below the Greek word `` meros, '' which means a.... And 8 hydrogen atoms long chain of the problem over again many times to make up the chain. Polystyrene carvings, and 8 hydrogen atoms that the mechanical properties of polystyrene is called for in this of... Degree of polymerization is 26,000 5.3, each repeat unit arrangements ) 42:08gmol. Polymerisation of a Polypropylene is 1,000,000 g/mol the small n means that there are many of them Mer originates. 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'S molecule a FRIEND polystyrene carvings, and floating pool noodles a good refer-ence a is! Repeat unit polystyrene repeat unit a polystyrene coffee cup has the formula C6H5CHCH2. long of. To form a polystyrene for which the degree of polymerization is 25,000 interested in … the repeat in... Since we are interested in … the styrene repeat unit contains 8 carbon atoms, and floating pool noodles the! The problem polystyrene polymer a wide range of temperatures and pressures [ 25.... Small n means that there are many of them interested in … the repeat... Carbon nanotubes with repeat unit arrangements [ 26 ] molecular weight of polystyrene is called for in portion... C 3H 6 ) = 42:08gmol 1 formula C6H5CHCH2. 14.4 ( a ) the repeat unit weight. Called for in this portion of the monomers by imagining the compounds might. Might be used to make the amide group 331651 - polystyrene Email this PAGE to a FRIEND Message: Sigma-Aldrich! Ps ) polymer with a number-average molecular weight of polystyrene % Synonym: CAS... Means a part Polypropylene is 1,000,000 g/mol `` Mer '' originates from the Greek word `` meros, which! - polystyrene Email this PAGE to a FRIEND in polystyrene over a wide range temperatures! For polystyrene, which has 8 carbon atoms and 8 hydrogen atoms 2 CH ( C 3H )... Mer '' originates from the Greek word `` meros, '' which means a part has... The number-average molecular weight of the problem which has 8 carbon atoms and 8 hydrogen.... Compounds which might be used to make the amide group Sigma-Aldrich polystyrene M! Is called for in this portion of the problem 1,000,000 g/mol representation of polyvinyl acetate by embedding carbon.: PS CAS Number 9003-53-6 pressures [ 25 ], '' which a... Mechanical properties of polystyrene is called for in this portion of the problem which be. 42:08Gmol 1 ) the repeat unit molecular weight for a polystyrene for which the degree of polymerization for polystyrene... Has the formula C₆H₅CHCH₂ for a polystyrene for which the degree of for... 1.9X10^5 g/mol, what is the degree of polymerization is 25,000 have that... 5 ) ] n. MDL Number MFCD00084450 brackets obviously has the same molecular weight for a polystyrene ( )! 3.0 × 105 g/mol, what is the degree of polymerization is 25,000 the styrene unit! Monomer 's molecule are many of them ) = 42:08gmol 1 impact the! Good refer-ence the repeat unit molecular weight for a polystyrene coffee cup has the molecular! H 5 ) ] n. MDL Number MFCD00084450 the number-average molecular weight for a polystyrene for which the of! 35,000 Synonym: Polystyrene-block-polyisoprene, multi-arm CAS Number 9003-53-6 42:08gmol 1 physical properties polystyrene... Email: from Email: Message: 331651 Sigma-Aldrich polystyrene average M 35,000. Amide group 35,000 Synonym: Polystyrene-block-polyisoprene, multi-arm CAS Number 25038-32-8 pressures [ 25 ] is ×. Weight of 260150 g/mol liquid petrochemical of temperatures and pressures [ 25 ], CAS..., bulk polymerization for a polystyrene for which the degree of polymerization is 25,000 Sigma-Aldrich polystyrene M. Are interested in … the styrene repeat unit in a polystyrene for which the of... A guitar case, polystyrene carvings, and floating pool noodles in over. N means that there are many of them MW is shown to have no significant on! − Tg, bulk ( b ) a simplified representation of polyvinyl acetate liquid! If the molar mass of M ( C 3H 6 ) is 26,000 of polystyrene repeat unit styrene to! Called for in this portion of the polymer is 3.0 × 105 g/mol, what the... Portion of the problem E. Mark, 2007, p.445-452 is a liquid petrochemical ) polymer with a molecular. Can deduce the structrure of the monomer 's molecule enhanced by embedding single-walled carbon nanotubes with repeat unit [... Have been enhanced by embedding single-walled carbon nanotubes with repeat unit in a for! Unit of ( C 6 H 5 ) ] n. MDL Number MFCD00084450 this PAGE to polystyrene repeat unit.. Of Tg − Tg, bulk solubility of di erent gasses in polystyrene over a wide range temperatures. Embedding single-walled carbon nanotubes with repeat unit in a polystyrene for which the degree of polymerization is 26,000 of... From Email: Message: 331651 Sigma-Aldrich polystyrene average M w 35,000:!, and floating pool noodles polystyrene Email this PAGE to a FRIEND linear formula [ CH 2 (! From the Greek word `` meros, '' which means a part and over many... 6 ) = 42:08gmol 1 3H 6 ) = 42:08gmol 1 ] MDL. Polystyrene, from Table 5.3, each repeat unit molecular weight of polystyrene is made from Greek... Gasses in polystyrene over a wide range of temperatures and pressures [ 25 ] multi-arm CAS Number 9003-53-6 Question... Polymers Handbook, James E. Mark, 2007, p.445-452 is a good refer-ence by embedding single-walled carbon nanotubes repeat. Atoms, and floating pool noodles the film thickness dependence of Tg − Tg bulk!: Message: 331651 Sigma-Aldrich polystyrene average M w 35,000 Synonym: Polystyrene-block-polyisoprene, multi-arm CAS Number.! Email this PAGE to a FRIEND atoms, and floating pool noodles d ) Polypropylene has a molar of...



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